Webadamantanetetrabenzoic acid ATB in THF, yielding guest-containing tetracarboxylic-based frameworks (TCF-1, TCF-2 and TCF-3, respectively). The porous frameworks were … Web19 okt. 2009 · The modular self-assembly of methanetetrabenzoic acid with similar linear linkers, phenazine and 4,4′-bipyridine, affords two different interpenetrating diamondoid frameworks which show a normal ...
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WebA solvothermal reaction of Zn(ii) salt with methanetetrabenzoic acid (H4MTB) and 1,4,8,11-tetraazacyclotetradecane (cyclam, CYC) created a new microporous … WebTerpyridine and quaterpyridine-based complexes allow wide light harvesting of the solar spectrum. Terpyridines, with respect to bipyridines, allow for achieving metal-complexes with lower band gaps in the metal-to-ligand transition (MLCT), thus providing a better absorption at lower energy wavelengths resulting in an enhancement of the solar light-harvesting … aemet chimillas
SBET areas, CO2, and H2 storage capacities of MOFs
WebSolid 1, after removal of guest molecules, exhibits selective gas adsorption behavior for H2, CO2, and O2 rather than N2 and CH4, suggesting possible applications in gas separation technologies. A fourfold interpenetrating diamondoid network, [{[Ni(cyclam)]2-(mtb)}(n)].8n H2O.4n DMF (1) (MTB=methanetetrabenzoate, DMF=dimethylformamide), has been … Webtetracarboxylic acids such as methanetetrabenzoic acid MTB and silanetetrabenzoic acid STB were described to form closely-packed architectures,11 although such tetracarboxylic ligands were often used for the synthesis of MOFs.12 Herein we have proved the generation of porous diamondoid 3D-architectures (tetracarboxylic WebCocrystallization of the commonly available organic primary amine, 4-chlorobenzylamine, with a series of organic acids gave a total of nine molecular salts with the compositions: (4-chlorobenzylamine): (p-toluenesulfonic acid) (1) [(HL+) · (ptsa−)], (4-chlorobenzylamine): (m-chlorobenzoic acid) (2) [(HL+) · (mcba−)], (4-chlorobenzylamine): (m-nitrobenzoic … kbc ラジオ 採用